Combustion characteristics of extruded nitramine double-base propellants

Document Type : Original Article

Authors

School of chemical Engineering, Military Technical College, Cairo, Egypt.

Abstract

Abstract
The burning rate-pressure relation of solid propellant is an exponential relation; this is means catastrophic combustion process in case of sudden increase in operating pressure. This study reports on novel approach to minimize the dependence of burning rate on the operating pressure using highly energetic nitramines (RDX). Nitramine-based double base propellants with RDX content up to 20 wt % were manufactured by solventless extrusion technology. The impact of RDX content on burning rate, specific impulse, exhaust velocity, and thrust were evaluated using small-scale ballistic evaluation rocket motor. Specific impulse (Is) was enhanced by 20 %. The action burning time (tb) was increased by 14 %. The total thrust impulse (IFT) was significantly improved by 22%. One of the main outcomes of this study is that burning rate pressure exponent (n) which was decreased significantly from 0.35 to 0.05. This novel ballistic performance means minimal change in burning rate with pressure variation. These novel findings confirmed that RDX has a dual function as energetic filler and as a platonizing agent. This is the first time ever RDX has been reported to act as a platonizing agent. It can be concluded that many advantages have been achieved with one shot.

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