Para-xylene Maximization-Part VI SHAPE-SELECTIVE PLATINUM-PROMOTED METHYLATION OF TOLUENE.

Document Type : Original Article

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Egyptian Petroleum Research Institute, P.O. Box 9540, Nasr City, Cairo 11787, Egypt.

Abstract

ABSTRACT
The need for increasing the production of para-xylene, which is the primary material for producing the polyester fibers, activated this research. Although alkylation reaction are acid catalyzed, we found that a Pt promoter activates this reaction by virtue of the presence of vacant d-orbital in the Pt atom. In this work, a series of catalysts containing 0.1, 0.2 or 0.3%Pt in HZSM-5 zeolite were tested for alkylating toluene with methanol, aiming to produce the xylenes and maximizing para-xylene production during a temperatures range of 300-500oC in presence of hydrogen flow in a continuous-flow fixed-bed reactor. The catalysts were characterized by temperature programmed desorption (TPD) of ammonia for acid sites distribution analysis and platinum dispersion in the catalysts by hydrogen chemisorption. Moreover, the diffusion resistance extent in the current catalysts during the current alkylation reaction has been evaluated via estimation of the Thiele modulus, ФL. The selectivity for para-xylene production was found to increase systematically with increasing the Pt content in the catalysts, whereas the unloaded zeolite did not follow this order. The ФL values calculated were accordingly found to increase also with increasing the Pt content in the catalysts. Although para-xylene was the highest on the 0.3%Pt/H-ZSM-5 catalyst, the heavy undesired trimethylbenzenes were the lowest to be formed on this catalyst.

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