The potentials of copper chromite nanoparticles on ammonium nitrate decomposition: Towards eco-friendly oxidizers for green solid propellants

Document Type : Original Article

Authors

1 Technical Research Centre, Cairo, Egypt.

2 Military Technical College, Kobry Elkobbah, Cairo, Egypt.

10.1088/1742-6596/2830/1/012013

Abstract

Ammonium perchlorate (AP) is the universal oxidizer for solid propellants; AP combustion is accompanied with the release of white smoke (HCl). HCl has raised an environmental concern; it could cause acidic rain and deteriorate the fertile soil. Chlorine free and eco-friendly oxidizers are highly appreciated for green solid propellants. Ammonium nitrate
(AN) could be the greener substitute for AP; yet AN expose low performance. Whereas AP demonstrated exothermic decomposition with the release of -733 J/g; AN demonstrated strong endothermic decomposition process of +1707 J/g. AN with strong endothermic decomposition process could render high burning rates. Copper chromite Nano catalyst of 45 nm was developed via hydrothermal synthesis. Copper chromite was integrated into AN matrix. Catalyzed AN
demonstrated advanced exothermic decomposition enthalpy of -1492 J/g. Catalysed AN experienced diminish in activation energy by - 41.5 %, and – 40.6 % using Kissinger and Ozawa models respectively. Copper chromite NPs could secure novel catalytic effect via condensed phase reactions of chromium, and copper ions with nitrate ions (NO-3) to develop NOx gases. This catalytic effect can secure alternative pathway with low energy barrier. Consequently,
catalysed AN can expose novel characteristics as a green eco-friendly oxidizer.

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